cse โข paper_1 โข thermal_physics
[UPSC CSE 2018] Thermodynamics (Q61, 20M)
If the temperature variation of heat capacity is known, how do you calculate the change of entropy during an isochoric process? According to Debye's theory of specific heat of a solid, the molar heat capacity of diamond crystal at constant volume varies with temperature (T) as follows: c_v=\frac{12}{5}\pi^{4}R\left(\frac{T}{\Theta}\right)^{3} where R is the molar gas constant =8.315\ \mathrm{J/mol\ K} and \Theta=2230\ \mathrm{K} for diamond. Calculate the change in entropy of diamond of 0.36 g mass when it is heated at constant volume from 0 K to 300 K.
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