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cse • paper_1 • thermal_physicscse-2007-subject-04-003

Equation of state — UPSC CSE 2007 Physics PYQ

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Establish the relation C_p - C_v = \left[ P + \left(\frac{\partial U}{\partial V}\right)_T \right] \left(\frac{\partial V}{\partial T}\right)_P Use it to find out an expression for C_p of one mole of a gas whose internal energy is given by U = cT - \frac{a}{V} and which satisfies the equation of state \left[ P + \frac{a}{V^2} \right](V - b) = RT. Here a, b and c are constants.

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